March 12, 1963
Mr. Jeremy Bernstein
The New Yorker Magazine
25 West 43 Street
New York, New York
Dear Mr. Bernstein,
During the production of EXPLORING THE UNIVERSE, I mentioned to you that a friend of mine, Kenneth Snelson, was working on a model of the atom. Some of his ideas have been recent1y published in Industrial Design magazine.
I remember well your skepticism, but you did sy that you would hear him out. For this reason, I am sending you a copy of his article.
I 'm sure that he would appreciate any consideration you would give to his work.
Sincerely,
Audrey Goldenstein
NEW YORK UNIVERSITY
GRADUATE SCHOOL OF
ARTS AND SCIENCE
WASHINGTON SQUARE, NEW YORK 3, N.Y.
DEPARTMENT OF PHYSICS TELEPHONE:
SPRING 7-2000
March 12, 1963
Dear Audrey Goldenstein;
In response to your note, I think the models are very
beautiful, but, as far as I can tell, their scientific basis is simply wrong.
Mr. Snelson gives a good popular account of the properties of the one electron
atom. He gets into trouble beginning in the section entitled electronic dilemma. In a many electron
atom the electrons do collide and interact. This is not a violation of the
Pauli principle or anything else. There are no exact orbits describable in
terms of simple quantum numbers in a many electron atom. There are approximate
quantum numbers. But there is an exact equation whose solutions give all of the
properties of such an atom. This equation cannot be solved exactly, but it can
be solved approximately, on machines. Such solutions describe the properties of
the heavy atoms to an desired degree of accuracy. There are, as far as I know,
no unsolved problems of principle in this field. It is a matter of solving the
equation as best one can. Many electron atoms are very complex. If you don't
believe it look at a photograph of the iron spectrum some time. There are no
simple Balmer series, but one observes a
jungle of lines. It is a fine art to assign any kind of quantum numbers to
these literally thousands, of observed lines. I do not see that Snelson model
sheds any light whatever on this problem nor on any other problem in quantum
theory.
I do not want to
discuss this any further.
Yours,
(signed) Jeremy Bernstein
PS: Perhaps his models are useful to chemists. I do not know
anything about chemistry and therefore have no opinion. Consult a chemist.
PSS: A colleague of mine just pointed out that Mr. Snelson
makes the common mistake of in identifying the 1s state of hydrogen with a
circular orbit. The 1s state goes through the nucleus as can he seen from the
fact that its wave function does not vanish at the origin.